Influence of partial oxidation of xanthate on flotability of gold minerals

Authors

DOI:

https://doi.org/10.15328/cb2026_43

Keywords:

oxidation, xanthate, dixanthogen, turboflotation generator, microflotation, gold minerals

Abstract

Losses of gold minerals with fine grades remain an urgent problem of modern flotation technology. Gold minerals associated with iron sulfides (pyrite, arsenopyrite) can be extracted using sulfhydryl collectors. As it is known, the maximum flotability of iron sulfides is observed in case of simultaneous presence on their surface of both xanthate and dixanthogen. The aim of the work is to study the effect of partial oxidation of amyl potassium xanthate (AKs) on the efficiency of flotation enrichment of gold-bearing sulfide ore. Partial oxidation of potassium amyl xanthate solution using turboflotation generator is proposed to obtain a collector including xanthate and dixanthogen in its composition. Testing of collectors AKs and AKs + AKsokisil. on sulfide gold-bearing ore showed that partial oxidation of xanthate to dixanthogen improves technological indicators of flotation. Partial oxidation of xanthate allows to increase gold recovery from 83.8 to 89.3 % at reduction of gold content in flotation tailings from 0.48 to 0.32 g/t. Turboflotation generator allows to increase gold recovery from 89.2 to 91.7 % at reduction of gold content in flotation tailings from 0.31 to 0.24 g/t.

Author Biographies

B.Ye. Daulet, Institute of Metallurgy and Ore Beneficiation, Satbayev University, Almaty, Kazakhstan

докторант, ведущий инженер лаборатории флотореагентов и обогащения, АО «Институт металлургии и обогащения», Satbayev University, Алматы, Казахстан; e-mail: b.d.e.metal@mail.ru

D.K. Turysbekov, Institute of Metallurgy and Ore Beneficiation, Satbayev University, Almaty, Kazakhstan

к.т.н., ассоциированный профессор, ведущий научный сотрудник лаборатории флотореагентов и обогащения, АО «Институт металлургии и обогащения», Satbayev University, Алматы, Казахстан;  e-mail: dula80@mail.ru

L.V. Semushkina, Institute of Metallurgy and Ore Beneficiation, Satbayev University, Almaty, Kazakhstan

к.т.н., ведущий научный сотрудник лаборатории флотореагентов и обогащения, АО «Институт металлургии и обогащения», Satbayev University, Алматы, Казахстан; e-mail: syomushkina.lara@mail.ru

S.M. Narbekova, Institute of Metallurgy and Ore Beneficiation, Satbayev University, Almaty, Kazakhstan

докторант, научный сотрудник лаборатории флотореагентов и обогащения, АО «Институт металлургии и обогащения», Satbayev University, Алматы, Казахстан; e-mail: s.narbekova@mail.ru

Zh.A. Kaldybayeva, Institute of Metallurgy and Ore Beneficiation, Satbayev University, Almaty, Kazakhstan

младший научный сотрудник лаборатории флотореагентов и обогащения, АО «Институт металлургии и обогащения», Satbayev University, Алматы, Казахстан; e-mail: arsenti73@mail.ru

A.M. Mukhamedilova , Institute of Metallurgy and Ore Beneficiation, Satbayev University, Almaty, Kazakhstan

младший научный сотрудник лаборатории флотореагентов и обогащения, АО «Институт металлургии и обогащения», Satbayev University, Алматы, Казахстан; e-mail: aigjlek_m@mail.ru

References

1. Miettinen T, Ralston J, Fornasiero D (2010) Mineral Eng 23(5):420–437. https://doi.org/10.1016/j.mineng.2009.12.006

2. Wang G, Evans GM, Jameson GJ (2016) Sep Purif Technol 170:155–172. https://doi.org/10.1016/j.seppur.2016.06.041

3. Rulyov N, Tussupbayev N, Turusbekov D, Semushkina L, Kaldybayeva Zh, (2018) Mineral Processing and Extractive Metallurgy Trans. Inst. Min. Metall C 127(3):160–168. https://doi.org/10.1080/03719553.2017.1351067

4. 4 Mambetaliyeva AR, Mamyrbayeva KK, Turysbekov DK, Dauletbakov TS, Barmenshinova MB (2022) Naukovyi Visnyk NHU 3:51-56. https://doi.org/10.33271/nvngu/2022-3/051

5. Semushkina LV, Tussupbayev NK, Turysbekov DK, Narbekova SM, Mukhanova AA (2022) Metalurgija 61(1):277-280. https://hrcak.srce.hr/262457

6. Тussupbayev NK, Rulyov NN, Kravtchenco ОV (2016) Mineral Processing and Extractive Metallurgy, Trans. Inst. Min. Metall 125:5-9. https://doi.org/10.1179/1743285515Y.0000000014

7. Yesengaziyev AM, Barmenshinova MB, Bilyalova SM, Mukhanova AA, Mukhamedilova AM (2020) Complex Use of Mineral Resources 3:65-75. https://doi.org/10.31643/2020/6445.28

8. Toktar G, Magomedov DR, Коizhanova AK, Abdyldaev NN, Bakraeva AN (2023) Complex Use of Mineral Resources 325(2):62-71. https://doi.org/10.31643/2023/6445.19

9. Fan M, Tao D, Honaker R, Luo Z (2010) Mining Science and Technology 20:641-671. https://doi.org/10.1016/S1674-5264(09)60259-3

10. Fan M, Tao D, Honaker R and Luo Z (2010) Mining Science and Technology 20(2):159-177. https://doi.org/10.1016/S1674-5264(09)60179-4

11. Calgaroto S, Azevedo A, Rubio J (2015) Int J Miner Process 137:64-70. https://doi.org/10.1016/j.minpro.2015.02.010

12. Ahmadi R, Khodadadi DA, Abdollahy M, Fan M (2014) International Journal of Mining Science and Technology 24:559–566. https://doi.org/10.1016/j.ijmst.2014.05.021

13. Ralston J, Fornasiero D, Hayes R (1999) Int J Miner Process 56:133–164. https://doi.org/10.1016/S0301-7516(98)00046-5

14. Ralston J, Dukhin SS, Mishchuk NA (2002) Adv Colloid Interfac 95:145–236. https://doi.org/10.1016/S0001-8686(00)00083-X

15. Özçelik S, Ekmekçi Z (2024) Mineral-Basel 14(9):914. https://doi.org/10.3390/min14090914

16. Geng Q, Han G, Wen S (2024) Mineral-Basel 14(10):1026. https://doi.org/10.3390/min14101026

17. Kenzhaliyev BK, Koizhanova AK, Atanova OV, Magomedov DR, Nurdin H (2024) Complex Use of Mineral Resources 329(2):63-72. https://doi.org/10.31643/2024/6445.17

18. Sun X, Yu J, Jin J, Sun H, Li Y, Han Y (2023) Separations 10(12):584. https://doi.org/10.3390/separations10120584

19. Liu W, Miller JD, Sun W, Hu Y (2022) Mineral-Basel 12(10):1310. https://doi.org/10.3390/min12101310

20. Chanturiya VA, Vigdergauz VE (2008) Electrochemistry of sulphides. Theory and practice of flotation [Elektrohimiya sul’fidov. Teoriya i praktika flotacii]. Ruda i Metally Publ., Moscow, Russia. 272 pр. (In Russian)

21. Khan GA, Gabrielova LI, Vlasova NS (1986) Flotation reagents and their application [Flotacionnye reagenty i ih primenenie].Nedra, Moscow, USSR. 271 pр. (In Russian)

22. Leonov SB, Komogortsev BV (1969) Aqueous solutions of butyl potassium xanthogenate, dixanthogen and their interaction with sulfide minerals [Vodnye rastvory butilovogo ksantogenata kaliya, diksantogena i ih vzaimodejstvie s sul’fidnymi mineralami]. Vost.-Sib. book publishing house, Irkutsk, Russia. 176 pр. (In Russian)

23. Chen TT (2002) JOM 54:20–22. https://doi.org/10.1007/BF02709181

24. Toktar G, Kaumetova DS, Koizhanova AK, Magomedov DR, Аtanova OV, Abdyldayev NN (2022) Otechestvennaya Geologiya 6:86-94. https://doi.org/10.47765/0869-7175-2022-10037

25. Barmenshinova MB, Motovilov IYU., Telkov ShA, Omar RS (2024) Complex Use of Mineral Resources 331(4):5-11. https://doi.org/10.31643/2024/6445.34

26. Bogudlova AI, Voyloshnikov GI, Matveeva TN (2017) Bulletin of Irkutsk State Technical University [Vestnik Irkutskogo gosudarstvennogo tekhnicheskogo universiteta] 21:12:195–202. https://doi.org/10.21285/1814-3520-2017-12-195-202. (In Russian)

27. Tusupbaev NK, Zhantasov NN, Omarov AT, Semushkin AV, Kasymbergebaev BT (2019) Method for multicomponent microflotation of finely disseminated ores of non-ferrous and precious metals and a device for its implementation. Patent for Utility Model of the Republic of Kazakhstan No. 4039 dated 07.06.2019, Bulletin No. 23. (In Russian)

28. Chanturiya VA, Lebedev VD, Lunin VD (1978) Study of the mechanism of xanthate and its derivatives adsorption on sulfides under electrochemical processing of flotation pulps. Combined mineral concentration methods [Izuchenie mekhanizma adsorbcii ksantata i ego proizvodnyh na sul’fidah pri elektrohimicheskoj obrabotke flotacionnyh pul’p. Kombinirovannye metody obogashcheniya mineralov]. Nauka Publ., Moscow, USSR. P.3-13. (In Russian)

29. Lotter NO, Bradshaw DJ (2010) Miner Eng 23 (11–13):945-951. https://doi.org/10.1016/j.mineng.2010.03.011

30. Chen Y, Chen J, Lan L, Yang M (2012) Miner Eng 27:65-71. https://doi.org/10.1016/j.mineng.2012.01.001

31. Gardner JR, Woods R (1977) Aust J Chem 30(5):981-991. https://doi.org/10.1071/CH9770981

32. Wu M, Liu R, Zhou Y, Hu Y, Sun W (2024) Sep Purif Technol 348:127815. https://doi.org/10.1016/j.seppur.2024.127815

33. Wu Z, Tao D, Tao Y, Ma G (2023) Miner Eng 201:108222. https://doi.org/10.1016/j.mineng.2023.108222

Published

2026-03-30

How to Cite

Daulet, B., Turysbekov, D., Semushkina, L., Narbekova, S., Kaldybayeva, Z., & Mukhamedilova , A. (2026). Influence of partial oxidation of xanthate on flotability of gold minerals. Chemical Bulletin of Kazakh National University, 117(1), In Press. https://doi.org/10.15328/cb2026_43